海洋沉积物中石英单矿物的化学分离   总被引：7，自引：1，他引：7  

万世明  蒋恒毅  李安春 《海洋地质与第四纪地质》2003,23(3):123-128

海洋沉积物中的石英作为陆源物质的标志性矿物,是古环境和古气候演化的信息载体,已成为古环境和古气候演化研究的重要替代指标.提供了改进了的化学分离海洋沉积物中石英单矿物的方法流程.在流程中的不同阶段可有效去掉全样中的生物组分、粘土矿物和长石等,取得海洋沉积物全样的总陆源矿物、石英+长石、石英的相对和绝对含量,通过计算可获得各种组分的通量,通过粒度分析可获得粒度数据.同一样品的17次重复实验表明,含量结果的平均相对误差仅为2.36%;显微镜和X射线衍射分析检查所分离出的石英纯度可达98%以上;激光粒度分析表明,化学试剂对石英的溶蚀作用不明显,不影响粒度分析结果.  相似文献   

光释光测年中石英样品提纯方法的改进   总被引：1，自引：0，他引：1  

李国强  赵晖  范育新  彭海梅  陈发虎 《地球科学进展》2008,23(3):284-289

为了解决光释光前处理中遇到的传统方法无法获得满足纯度石英的问题,通过大量对比实验,结合玻璃工艺中石英分离研究成果,最后获得了新的石英提纯流程,与传统方法相比,新方法通过化学分离避免了密度变化对石英长石分离的影响,从而解决了斜长石和岩屑在传统的重液分离中无法剔除的问题,新方法能够获得满足纯度要求和量要求的石英,同时,新方法比传统方法实验室工作效率更高。  相似文献   

Normative quartz as an indicator of the mass transfer intensity during the postmagmatic alteration of the Botuobinskaya pipe kimberlites (Yakutia)     

V.B. Vasilenko  A.V. Tolstov  V.A. Minin  L.G. Kuznetsova  N.V. Surkov 《Russian Geology and Geophysics》2008,49(12):894-907

The intensity of postmagmatic processes in the Botuobinskaya pipe kimberlites was estimated from the calculated content of normative secondary quartz (Q). Several simple algorithms are proposed to calculate the Q content from chemical analyses of kimberlites. Ten groups of altered kimberlites have been recognized from the Q contents. The contents of MgO, some trace elements, and LREE in the groups, the contents of Cr and Ca of crimson garnets, the diamond contents of kimberlites, and the average weight of diamonds decrease as the Q content increases. It is shown that the negative SiO₂–MgO correlation is the most effective indicator of the postmagmatic alteration of kimberlites. As the degree of their secondary alteration increases, the kimberlites transform into an assemblage of quartz and clay minerals enriched in some trace elements and almost completely lacking REE and diamonds.  相似文献   

Rock magnetic record of Cenozoic lake sediments from the Linxia basin and aridification of the Asian inland   总被引：1，自引：0，他引：1  

Xianhai Xu  Xiaomin Fang 《Frontiers of Earth Science》2008,2(2):217-224

High resolution research of rock magnetic records and quartz sands from the Maogou Section in the Linxia basin reveals that after a relatively stable environment between 13.07 Ma and 8.6 Ma, the basin was gradually influxed by eolian dusts at about 8.6 Ma, with two rapid increases at about 6.4 Ma and 5.3 Ma, respectively. The study suggests that drying of northwest China began at 8.6 Ma and strengthened rapidly at about 6.4 Ma and 5.3 Ma. __________ Translated from Marine geology & Quaternary geology, 2007, 27(4): 103–110 [译自: 海洋地质与第四纪地质]  相似文献   

Spinel–sapphirine–quartz bearing composite inclusion within garnet from an ultrahigh-temperature pelitic granulite: Implications for metamorphic history and P–T path     

Toshiaki Tsunogae  M. Santosh 《Lithos》2006,92(3-4):524-536

We report here a multiphase mineral inclusion composed of quartz, plagioclase, K-feldspar, sapphirine, spinel, orthopyroxene, and biotite, in porphyroblastic garnet within a pelitic granulite from Rajapalaiyam in the Madurai Granulite Block, southern India. In this unique textural association, hitherto unreported in previous studies, sapphirine shows four occurrences: (1) as anhedral mineral between spinel and quartz (Spr-1), (2) subhedral to euhedral needles mantled by quartz (Spr-2), (3) subhedral to anhedral mineral in orthopyroxene, and (4) isolated inclusion with quartz (Spr-4). Spr-1, Spr-2, and Spr-4 show direct grain contact with quartz, providing evidence for ultrahigh-temperature (UHT) metamorphism at temperatures exceeding 1000 °C. Associated orthopyroxene shows high Mg/(Fe + Mg) ratio ( 0.75) and Al₂O₃ content (up to 9.6 wt.%), also suggesting T > 1050 °C and P > 10 kbar during peak metamorphism.

Coarse spinel (Spl-1) with irregular grain morphology and adjacent quartz grains are separated by thin films of Spr-1 and K-feldspar, suggesting that Spl-1 and quartz were in equilibrium before the stability of Spr-1 + quartz. This texture implies that the P–T conditions of the rock shifted from the stability field of spinel + quartz to sapphirine + quartz. Petrogenetic grid considerations based on available data from the FMAS system favour exhumation along a counterclockwise P–T trajectory. The irregular shape of the inclusion and chemistry of the inclusion minerals are markedly different from the matrix phases suggesting the possibility that the inclusion minerals could have equilibrated from cordierite-bearing silicate-melt pockets during the garnet growth at extreme UHT conditions.  相似文献   

Petrogenesis and tectonic setting of Cadomian felsic igneous rocks, Sandıklı area of the western Taurides, Turkey     

Semih Gürsu  M. Cemal Göncüoglu 《International Journal of Earth Sciences》2006,95(5):741-757

In the Sandıklı (Afyon) region, western Taurides, the Late Proterozoic rocks of the Sandıklı basement complex are composed of low-grade meta-sedimentary rocks (Güvercinoluk Formation) intruded by felsic rocks (Kestel Cayı Porphyroid Suite, KCPS). The KCPS is a deformed and highly sheared, dome-shaped rhyolitic body with a granitic core. Quartz porphyry dikes intrude both the slightly metamorphic igneous and the sedimentary rocks of the basement complex. Both the quartz porphyries and rhyolites were converted into mylonites with relict igneous textures. Geochemical data show that these felsic igneous rocks are subalkaline and mainly granitic in composition with SiO₂ >72 wt% and Al₂O₃ >11.5 wt%. The chondrite-normalized incompatible trace element patterns are characterized by distinct negative Rb, Nb, Sr, P, Ti, and Eu with enrichment in Th, U, La, Ce, Nd, Sm, and Zr. The REE patterns of the felsic rocks indicate a strong enrichment in LREE but display slightly flat HREE patterns. According to geochemical characteristics and petrogenetic modeling, extrusive and intrusive rocks of the KCPS were probably derived from an upper continental crustal source (partial melting of granites/felsic rocks) by 18–20% fractional melting plus 18–20% Rayleigh fractional crystallization, which seems to be the most effective igneous process during the crystallization of the KCPS. Single zircon age data from the granitoids and fossils from the disconformably overlying sedimentary successions indicate that the metamorphism and the igneous event in the Taurides are related to the Cadomian orogeny. Based on the geological, geochemical and petrogenetic correlation of the post-collisional granitoids it is further suggested that the Tauride belt in western central Turkey was in a similar tectonic setting to the Gondwanan terranes in North Africa (Younger Granitoids) and southern Europe (Spain, France, Bohemia, Brno Massifs) during the Late Cadomian period.  相似文献   

Adsorption of Pentachlorophenol onto Oxide and Clay Minerals： Surface Reaction Model and Environmental Implications     

WU Daqing DIAO Guiyi YUAN Peng PENG Jinlian 《《地质学报》英文版》2006,80(2):192-199

The adsorption of pentachlorophenol （PCP） onto quartz, kaolinite, illite, montmorillonite and iron oxides has been investigated by batch equilibrium techniques. The pH-dependent isotherms are curves with peak values, the position of which is at about pH = 5-6 depending on the mineral species. Based on distribution of both speciation of surface hydroxyls on minerals and PCP in solution a surface reaction model involving surface complexation and surface electrostatic attraction is presented to fit the pH-dependent isotherms, and both reaction constants are calculated. The results show that on quartz and phyllosilicate minerals the predominant adsorption reaction is surface complexation, meanwhile both of surface electrostatic attraction and surface complexation are involved on the iron oxide minerals. The reaction constants of surface electrostatic adsorption are usually one to three orders in magnitude, larger than that of surface complexation. The concentration-dependent isotherms can be well fitted by Langmnir equation with the correlation coefficient R〉0.93 for kaolinite and iron oxides. The maximum adsorption is found in the order： hematite 〉 lepidocrocite 〉 goethite 〉 kaolinite 〉 quartz 〉 montmorillonite ≈ illite, which can be interpreted by consideration of both reaction mechanism and surface hydroxyl density. The significant adsorption of PCP onto mineral surfaces suggests that clay and iron oxide minerals will play an important role as HIOCs are adsorbed in laterite or latertoid soil, which is widespread in South China.  相似文献   

微波消解-火焰原子吸收光谱法测定石英砂中的氧化钙和氧化镁     

鲁青庆 《岩矿测试》2005,24(4):314-316

采用微波消解-硼酸络合-火焰原子吸收光谱法测定石英砂中的氧化钙和氧化镁。样品在MK-Ⅲ型实验室微波炉上消解,消解压力为2.0 MPa、消解时间为5 m in,以硼酸络合消除氢氟酸的影响。方法已用于实际样品的测定,7次测定的相对标准偏差(RSD)小于5%,加标回收率为95.0%~104.2%。  相似文献   

CCSD主孔1113~1600 m花岗质片麻岩单元的变形构造特征   总被引：3，自引：0，他引：3       下载免费PDF全文

唐哲民柴耀楚  陈世忠陈方远 《中国地质》2005,32(2):265-275

中国大陆科学钻探(CCSD)主孔2000m岩性剖面揭示了1113～1600m花岗质片麻岩段为地表北苏鲁超高压花岗质变质岩剪切构造叠覆岩片中的石湖镇构造岩片的花岗质片麻岩的下延部分。本单元之上下界线为韧性剪切带,内部发育小型韧性剪切变形,仅局部可见旋转碎斑体系等剪切指向标志,以SE向NW的逆冲剪切指向为主,其次为NW向SE的正滑剪切指向,并主要发育于较软弱夹层内,后者成为苏鲁地区存在伸展型穹隆构造的新证据;在1140～1280m岩性段内发育断续、较弱的拉伸线理,拉伸线理总体向SE倾伏,倾伏角为10～36°;花岗质片麻岩单元内部分石英以多晶石英条带的形式存在,花岗质片麻岩主要矿物长石基本没有动态重结晶现象,仅具较弱的形态拉长特征(X∶Z=2左右),总体面理倾向170°E,倾角平均20°,明显不同于其他岩性单元内的面理产状,可能主要代表折返变形之前的近东西向构造,而其他岩性单元受折返变形影响较大,其面理产状主要代表折返阶段形成的NE-NNE向构造;运用电子背散射(EBSD)技术进行石英组构分析并与费氏台测定对比,表明1113～1600m花岗质片麻岩单元经历了中—低温变形,局部残留有高温组构,剪切指向主要为SE向NW的逆冲,其中高温组构与中温组构均显示为SE向NW的逆冲剪切指向,反映折返早期与折返主期岩片的相对剪切方向一  相似文献   

一种新的储层孔隙成因类型--石英溶解型次生孔隙   总被引：26，自引：2，他引：26  

邱隆伟  姜在兴  陈文学  李晓红  熊志东 《沉积学报》2002,20(4):621-627

石英作为碎屑岩储层中的一种难溶组分,普遍认为它和次生孔隙的形成关系不十分密切。研究认为泌阳凹陷核桃园组储层中的碎屑石英颗粒存在明显的溶解现象,并形成以石英直接溶解型孔隙为主的储集空间特征。石英颗粒被溶解的部分在薄片中所占的范围为 2 %～ 7%者常见,高者达 8%以上,在总孔隙中所占的相对含量也多数在10 %～ 35 %之间,早成岩B期是其最主要形成期。石英溶解型次生孔隙的大量存在为碎屑岩储层中SiO₂ 胶结物及次生孔隙成因等问题的解释以及储层预测和评价提供了新的可能性。  相似文献